Sodium triacetoxyborohydride
CAS:56553-60-7
MOQ:1KG
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Description
Sodium triacetoxyborohydride CAS 56553-60-7 Product Information
Product Name: | Sodium Triacetoxyborohydride (Technical Grade) |
Synonyms: | SODIUM TRIACETOXYBOROHYDRIDE;sodiumtriacetoxyborohydride,calselect?stab;Sodium triacetohydroborate, Triacetohydroborate sodium salt;Sodiumtriacetoxyborohydride,95%;Sodium tris(acetoxy)borohydride, Tris(acetoxy)hydroborate sodium salt;Sodium tris(acetoxy)hydroborate 97%;Sodium Triacetoxyborohydride (Technical Grade);SodiuM triacetoxyborohydride 97% |
CAS NO: | 56553-60-7 |
Molecular Weight: | 211.94 |
Molecular Formula: | C6H10BNaO6 |
Boiling Point: | 111.1℃[at 101 325 Pa] |
Melting point: | 116-120 °C (dec.) (lit.) |
Density: | 1.36[at 20℃] |
Appearance: | White to Off-White Solid |
Applications: | Sodium triacetoxyborohydride is a mild reagent that exhibits remarkable selectivity as a reducing agent. It reduces aldehydes but not ketones. |
Solubility: | Soluble in dimethyl sulfoxide, methanol, benzene, toluene, terahydrofuran, dioxane and methylene chloride. |
Storage: | Inert atmosphere, Room Temperature |
sodium cyanoborohydride vs sodium triacetoxyborohydride
TriAcetOxyBorohydride is a safer reducing agent than Sodium cyanoborohydride with comparable reactivity . The boron-hydrogen bond is stabilized by the steric and electron-withdrawing effects of the acetoxy groups, making sodium triacetoxyborohydride a mild reducing agent.
sodium triacetoxyborohydride CAS 56553-60-7 synthesis
Sodium triacetoxyborohydride can be prepared by protonolysis of sodium borohydride with acetic acid: NaBH4 + 3 HO2CCH3 → NaBH(O2CCH3)3 + 3 H.
sodium triacetoxyborohydride safety/sodium triacetoxyborohydride hazards
Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Handle under inert gas, protect from moisture.
sodium triacetoxyborohydride CAS 56553-60-7 reductive amination
Sodium triacetoxyborohydride is presented as a general reducing agent for the reductive amination of aldehydes and ketones. Procedures for using this mild and selective reagent have been developed for a wide variety of substrates.
sodium triacetoxyborohydride solubility/sodium triacetoxyborohydride solubility in organic solvents
Soluble in dimethyl sulfoxide, methanol, benzene, toluene, terahydrofuran, dioxane and methylene chloride.
sodium triacetoxyborohydride reaction with water
Sodium triacetoxyborohydride hydrolyzes in water to release hydrogen, which is flammable.
sodium triacetoxyborohydride decomposition
n case of an uptake via oral, inhalation or dermal route, Sodium triacetoxyborohydride comes into contact with wet mucosa in the mouth, respiratory tract or sweat on the skin, and consequently decomposes to final products hydrogen and boric acid.
Transit time | You will normally receive your parcel within 7-15 working days after shipment (this may be delayed in special circumstances, such as Chinese New Year). |
Receiving method | Generally we will send the goods by courier or special line, of course, if the goods themselves in the local warehouse have goods, also support self-pickup, depending on the circumstances. |
Overseas warehouse | We have overseas warehouses in some European countries and Australia, such as Germany, Russia and Australia. |
Delivery Method | WGP will ship via courier companies such as DHL, FedEx, UPS, TNT or EMS. |
About After Sales | Within 7 days of your receipt of the goods if you find any problems with the goods (broken packaging, less hair, etc.) please feel free to contact our sales, we will help you deal with it in time. |
Additional information
Melting Point | 116-120 °C (dec.) (lit.) |
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Solubility | Soluble in dimethyl sulfoxide, methanol, benzene, toluene, terahydrofuran, dioxane and methylene chloride. |
Color | White |
Form | Powder |
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